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Unprecedented Sulfone‐Functionalized Metal–Organic Frameworks and Gas‐Sorption Properties
Author(s) -
Neofotistou Eleftheria,
D. Malliakas Christos,
N. Trikalitis Pantelis
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200900341
Subject(s) - sulfone , sorption , metal organic framework , selectivity , ligand (biochemistry) , metal , materials science , chemistry , chemical engineering , inorganic chemistry , organic chemistry , adsorption , catalysis , engineering , biochemistry , receptor
Gas storage : A new, sulfone‐functionalized dicarboxylate‐based ligand (see figure) is capable of directing the formation of novel metal–organic frameworks with unprecedented organic and inorganic secondary building units. A high CO 2 uptake with remarkable selectivity over CH 4 , N 2 , and H 2 was observed at near‐ambient temperature.