Torsional Photoisomerization Proceeding Adiabatically Through a Volume‐Conserving Pathway in Uninhibited Fluid Media | Zendy

Balomenou Ioanna | Zendy; Pistolis George | Zendy

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Torsional Photoisomerization Proceeding Adiabatically Through a Volume‐Conserving Pathway in Uninhibited Fluid Media

Author(s) -

Balomenou Ioanna,

Pistolis George

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900306

Subject(s) - photoisomerization , excited state , singlet state , chemistry , photochemistry , twist , singlet oxygen , rotation (mathematics) , atom (system on chip) , atomic physics , oxygen , physics , catalysis , organic chemistry , isomerization , computer science , embedded system , biochemistry , geometry , mathematics

Doing the hula twist? A photochemically stimulated inversion of an sp 2 ‐hybridized oxygen atom upon simultaneous rotation of two adjacent bonds may be possible in a pure singlet excited potential energy surface in uninhibited fluid media (see scheme).

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