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Iron Salts in the Catalyzed Synthesis of 5‐Substituted 1 H ‐Tetrazoles
Author(s) -
Bonnamour Julien,
Bolm Carsten
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200900169
Subject(s) - yield (engineering) , catalysis , trimethylsilyl azide , chemistry , azide , aryl , trimethylsilyl , environmentally friendly , organic chemistry , combinatorial chemistry , medicinal chemistry , materials science , biology , ecology , alkyl , metallurgy
Clicking iron : Cheap and environmentally friendly [Fe(OAc) 2 ] is used for the catalysis of cycloadditions between aryl nitriles and trimethylsilyl azide to prepare substituted 1 H ‐tetrazoles in good yield (see scheme).