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Palladium‐Catalyzed Carbon–Carbon Bond Formation and Cleavage of Organo(hydro)fullerenes
Author(s) -
Nambo Masakazu,
Itami Kenichiro
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200900022
Subject(s) - palladium , catalysis , fullerene , bond cleavage , chemistry , cleavage (geology) , carbon fibers , coupling reaction , reinforced carbon–carbon , photochemistry , organic chemistry , materials science , composite number , composite material , fracture (geology)
Palladium can tailor fullerenes : Palladium catalysts enable a number of CH bond transformations of organo(hydro)fullerene. In addition to anticipated coupling reactions (CH bond allylation and arylation), an unexpected new CH bond dimerization reaction and CC bond‐cleavage reaction were also uncovered.
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