Premium
A Porous Coordination Polymer with Accessible Metal Sites and its Complementary Coordination Action
Author(s) -
Sakamoto Hirotoshi,
Matsuda Ryotaro,
Bureekaew Sareeya,
Tanaka Daisuke,
Kitagawa Susumu
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200802730
Subject(s) - coordination polymer , metal , polymer , porosity , materials science , action (physics) , metal organic framework , porous medium , single crystal , surface (topology) , crystallography , nanotechnology , chemistry , composite material , physics , organic chemistry , metallurgy , geometry , adsorption , quantum mechanics , mathematics
Broken switch : Guest‐accessible metal sites are generated on the pore surface of a porous coordination polymer (see figure) through the complementary coordination‐bond rearrangement in a single‐crystal‐to‐single‐crystal fashion, which is triggered by the removal of coordinated water.