A Binuclear Cu II  Metallacycle Capable of Discerning between Pyrazine and Its Different Methyl‐Substituted Derivatives Based on Reversible Intracage Metal–Ligand Binding | Zendy

Hou GuiGe | Zendy; Ma JianPing | Zendy; Sun Ting | Zendy; Dong YuBin | Zendy; Huang RuQi | Zendy

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A Binuclear Cu II Metallacycle Capable of Discerning between Pyrazine and Its Different Methyl‐Substituted Derivatives Based on Reversible Intracage Metal–Ligand Binding

Author(s) -

Hou GuiGe,

Ma JianPing,

Sun Ting,

Dong YuBin,

Huang RuQi

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200802690

Subject(s) - metallacycle , pyrazine , ligand (biochemistry) , metal , chemistry , stereochemistry , medicinal chemistry , physics , x ray crystallography , organic chemistry , receptor , biochemistry , diffraction , optics

Squashy cage : A flexible, spongelike, and reversible metal‐binding Cu 2 L 2 cage that can adjust its internal space in response to pyrazine and its derivatives based on a recognition sequence of pyrazine, 2,5‐dimethylpyrazine, and 2‐methylpyrazine (see figure) is described.

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