A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes: Application to the One‐Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine | Zendy

Zeng Xiaoming | Zendy; Frey Guido D. | Zendy; Kousar Shazia | Zendy; Bertrand Guy | Zendy

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A Cationic Gold(I) Complex as a General Catalyst for the Intermolecular Hydroamination of Alkynes: Application to the One‐Pot Synthesis of Allenes from Two Alkynes and a Sacrificial Amine

Author(s) -

Zeng Xiaoming,

Frey Guido D.,

Kousar Shazia,

Bertrand Guy

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200802626

Subject(s) - hydroamination , cationic polymerization , intermolecular force , catalysis , amine gas treating , chemistry , alkyne , polymer chemistry , organic chemistry , combinatorial chemistry , molecule

Two very distinct chemical reactions, yet a single catalyst : A gold complex promotes the formation of tertiary enamines from a variety of terminal and internal alkynes. Subsequent addition of a terminal alkyne to the reaction mixture affords allenes (see scheme).

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