Energetic Ethylene‐ and Propylene‐Bridged Bis(nitroiminotetrazolate) Salts | Zendy

Joo YoungHyuk | Zendy; Shreeve Jean'ne M. | Zendy

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Energetic Ethylene‐ and Propylene‐Bridged Bis(nitroiminotetrazolate) Salts

Author(s) -

Joo YoungHyuk,

Shreeve Jean'ne M.

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200802326

Subject(s) - detonation , ethylene , standard enthalpy of formation , infrared spectroscopy , chemistry , elemental analysis , spectroscopy , analytical chemistry (journal) , inorganic chemistry , organic chemistry , catalysis , explosive material , physics , quantum mechanics

High energy density materials with ethylene‐ and propylene bis(5‐nitroiminotetrazolate) as the anions are reported; all salts were fully characterized by IR, and 1 H, 13 C, and 15 N NMR spectroscopy as well as elemental analyses. In addition, the heats of formation (Δ H f ) and the detonation pressures ( P ) and velocities ( D ) were calculated.The synthesis and detonation properties of high energy density materials with ethylene‐ and propylene bis(nitroiminotetrazolate) as the anions are reported; all salts were fully characterized by IR, and 1 H, 13 C, and 15 N NMR spectroscopy as well as elemental analyses. In addition, the heats of formation (Δ H f ) were calculated with the Gaussian 3.0 suite of programs. By using the experimental values for the densities of the nitroiminotetrazolate salts, the detonation pressures ( P ) and velocities ( D ) were calculated using Cheetah 5.0.

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