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Synthesis of Diarylamines Catalyzed by Iron Salts
Author(s) -
Correa Arkaitz,
Carril Mónica,
Bolm Carsten
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200802018
Subject(s) - acetanilide , catalysis , combinatorial chemistry , chemistry , organic chemistry
Fe shall overcome! A complementary procedure for the synthesis of diarylamines consisting of an iron‐catalyzed N ‐arylation of acetanilides followed by a subsequent deprotection step is presented. This protocol overcomes the previously observed limitations to prepare such compounds by iron‐catalyzed arylations of anilines.