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The First Flights of a Molecular Shuttle Transporting Elements: Easy One‐pot Formation of Organic Cyclic Arsanes, Stibanes and Bismutanes
Author(s) -
Baccolini Graziano,
Boga Carla,
Mazzacurati Marzia,
Micheletti Gabriele
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200802007
Subject(s) - reagent , antimony , bismuth , arsenic , catalysis , chemistry , combinatorial chemistry , organic chemistry
Maiden voyage : New arsenic‐, antimony‐ and bismuth‐donor reagents ( 1 b – d ) are used in a one‐pot synthesis of cyclic arsanes, stibanes and bismutanes through a procedure in which the simultaneous formation of three CAs, CSb or CBi bonds is achieved. At the end of the reaction, the element‐donor reagent can be easily re‐formed “in situ” and recycled, as in a catalytic process.