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Metal‐Tuned Photochemistry of Metallocene‐Substituted Chromium(0)–Carbene Complexes
Author(s) -
Lage Marta L.,
Fernández Israel,
Mancheño María J.,
GómezGallego Mar,
Sierra Miguel A.
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200802005
Subject(s) - chromium , metallocene , carbene , metal , photochemistry , chemistry , polymer chemistry , organic chemistry , catalysis , polymer , polymerization
Ferrocene or ruthenocene? Computational (DFT) methods predicted a metal‐dependent photochemistry for metallocenyl–chromium(0)–carbene complexes (see scheme). These theoretical predictions are fully confirmed by the experimental results.

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