A Highly Site‐, Regio‐, and Stereoselective Lewis Acid Catalyzed Formal [3+3] Cycloaddition of Methylenecyclopropane‐1,1‐Diesters with C,N‐Diarylnitrones | Zendy

Hu Bao | Zendy; Zhu Jianlin | Zendy; Xing Siyang | Zendy; Fang Jie | Zendy; Du Ding | Zendy; Wang Zhongwen | Zendy

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A Highly Site‐, Regio‐, and Stereoselective Lewis Acid Catalyzed Formal [3+3] Cycloaddition of Methylenecyclopropane‐1,1‐Diesters with C,N‐Diarylnitrones

Author(s) -

Hu Bao,

Zhu Jianlin,

Xing Siyang,

Fang Jie,

Du Ding,

Wang Zhongwen

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200801990

Subject(s) - methylenecyclopropane , cycloaddition , stereoselectivity , chemistry , lewis acids and bases , catalysis , stereochemistry , medicinal chemistry , organic chemistry

Another pathway : A new type of Lewis acid promoted [3+3] cycloaddition of methylenecyclopropane‐1,1‐diesters with C,N‐diarylnitrones is disclosed. This cycloaddition is highly site‐, regio‐, and stereoselective and proceeds in moderate‐to‐excellent yields. A three‐component one‐pot version of the cycloaddition is also reported.

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