Premium
Exploring the Reactivity of C(sp 3 )‐Cyclometalated Ir III Compounds in Hydrogen Transfer Reactions
Author(s) -
Azerraf Clarite,
Gelman Dmitri
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200801728
Subject(s) - reactivity (psychology) , hydrogen , chemistry , characterization (materials science) , thermal stability , stereochemistry , organic chemistry , materials science , nanotechnology , medicine , alternative medicine , pathology
Abstract The manuscript describes the synthesis and full characterization of a new PC(sp 3 )P‐based cyclometalated Ir III complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C(sp 3 )‐ metalated compounds.