Exploring the Reactivity of C(sp 3 )‐Cyclometalated Ir III  Compounds in Hydrogen Transfer Reactions | Zendy

Azerraf Clarite | Zendy; Gelman Dmitri | Zendy

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Exploring the Reactivity of C(sp 3 )‐Cyclometalated Ir III Compounds in Hydrogen Transfer Reactions

Author(s) -

Azerraf Clarite,

Gelman Dmitri

Publication year - 2008

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200801728

Subject(s) - reactivity (psychology) , hydrogen , chemistry , characterization (materials science) , thermal stability , stereochemistry , organic chemistry , materials science , nanotechnology , medicine , alternative medicine , pathology

The manuscript describes the synthesis and full characterization of a new PC(sp 3 )P‐based cyclometalated Ir III complex that manifests an exceptional thermal stability, as well as outstanding reactivity in hydrogen transfer reactions. The described compound represents the first example of a new family of stable C(sp 3 )‐ metalated compounds.

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