Reversible Conversion of Electronic Structures in a Cyclic Octacopper Complex | Zendy

Kawamoto Tatsuya | Zendy; Nishiwaki Masato | Zendy; Nishijima Makiko | Zendy; Nozaki Koichi | Zendy; IgashiraKamiyama Asako | Zendy; Konno Takumi | Zendy

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Reversible Conversion of Electronic Structures in a Cyclic Octacopper Complex

Author(s) -

Kawamoto Tatsuya,

Nishiwaki Masato,

Nishijima Makiko,

Nozaki Koichi,

IgashiraKamiyama Asako,

Konno Takumi

Publication year - 2008

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200801614

Subject(s) - delocalized electron , core (optical fiber) , chemistry , key (lock) , computer science , information retrieval , stereochemistry , crystallography , organic chemistry , telecommunications , computer security

Cyclic copper complex : A coordination compound with a cyclic ladder Cu 8 S 8 structure showed a clear interconversion between dicationic, monocationic, and neutral species (see graphic). These octacopper complexes are regarded as a new type of non‐innocent complex, and the dicationic and monocationic species in which radical(s) are delocalized over the Cu 8 S 8 core, give an intense near‐IR absorption band.

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