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Titanosilsesquioxane Anchored on Mesoporous Silicas: A Novel Approach for the Preparation of Heterogeneous Catalysts for Selective Oxidations
Author(s) -
Carniato Fabio,
Bisio Chiara,
Boccaleri Enrico,
Guidotti Matteo,
Gavrilova Elena,
Marchese Leonardo
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200801241
Subject(s) - mesoporous material , catalysis , mesoporous silica , covalent bond , materials science , heterogeneous catalysis , nanotechnology , surface modification , mesoporous organosilica , chemical engineering , chemistry , organic chemistry , engineering
Throw out the anchor! A new approach for the preparation of heterogeneous catalysts based on a covalent anchoring of an innovative multifunctional titanosisesquioxane on the inner surface silanols of mesoporous silicas (SBA‐15 and non‐ordered silica) is proposed (see figure).