Time‐Evolving Self‐Organization and Autonomous Structural Adaptation of Cobalt(II)–Organic Framework Materials with scu and pts Nets | Zendy

Wu JingYun | Zendy; Yang ShangLi | Zendy; Luo TzuooTsair | Zendy; Liu YenHsiang | Zendy; Cheng YiWei | Zendy; Chen YenFu | Zendy; Wen YuhSheng | Zendy; Lin LeeGin | Zendy; Lu KuangLieh | Zendy

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Time‐Evolving Self‐Organization and Autonomous Structural Adaptation of Cobalt(II)–Organic Framework Materials with scu and pts Nets

Author(s) -

Wu JingYun,

Yang ShangLi,

Luo TzuooTsair,

Liu YenHsiang,

Cheng YiWei,

Chen YenFu,

Wen YuhSheng,

Lin LeeGin,

Lu KuangLieh

Publication year - 2008

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200800758

Subject(s) - cobalt , benzene , net (polyhedron) , adaptation (eye) , product (mathematics) , key (lock) , chemistry , crystallography , stereochemistry , computer science , biology , organic chemistry , mathematics , neuroscience , operating system , geometry

Going where? The spontaneous, dynamic adjustment of equilibrium condition (K I /Co II ratio) is found to be a key factor in switching the assembly direction of Co II and K 4 btec (btec=benzene‐1,2,4,5‐tetracarboxylate). Compound 1 with a rare scu net was generated within the first three days. A few days later a new product—compound 2 with a pts net—autonomously formed.

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