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Time‐Evolving Self‐Organization and Autonomous Structural Adaptation of Cobalt(II)–Organic Framework Materials with scu and pts Nets
Author(s) -
Wu JingYun,
Yang ShangLi,
Luo TzuooTsair,
Liu YenHsiang,
Cheng YiWei,
Chen YenFu,
Wen YuhSheng,
Lin LeeGin,
Lu KuangLieh
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200800758
Subject(s) - cobalt , benzene , net (polyhedron) , adaptation (eye) , product (mathematics) , key (lock) , chemistry , crystallography , stereochemistry , computer science , biology , organic chemistry , mathematics , neuroscience , operating system , geometry
Going where? The spontaneous, dynamic adjustment of equilibrium condition (K I /Co II ratio) is found to be a key factor in switching the assembly direction of Co II and K 4 btec (btec=benzene‐1,2,4,5‐tetracarboxylate). Compound 1 with a rare scu net was generated within the first three days. A few days later a new product—compound 2 with a pts net—autonomously formed.