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Solid‐Phase Synthesis of Transition‐Metal Complexes
Author(s) -
Heinze Katja,
Beckmann Manuela,
Hempel Klaus
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200800697
Subject(s) - ruthenium , covalent bond , transition metal , ferrocene , terpyridine , metal , solid phase synthesis , chemistry , combinatorial chemistry , materials science , polymer chemistry , nanotechnology , organic chemistry , catalysis , peptide , biochemistry , electrode , electrochemistry
This overview highlights recent progress in the field of selective construction of linear, oligonuclear transition‐metal complexes by using solid‐phase synthesis procedures. Two general protocols have been identified: formation of coordinative bonds between metal centres and bridging ligands and formation of covalent bonds between preformed kinetically inert transition‐metal‐containing building blocks in the chain growth step. Currently available suitable building blocks for the second approach are based on ferrocene units, bis(terpyridine)–ruthenium(II) moieties or metal porphyrins.