N‐Bridged Diiron Phthalocyanine Catalyzes Oxidation of Benzene with H 2 O 2  via Benzene Oxide with NIH Shift Evidenced by Using 1,3,5‐[D 3 ]Benzene as a Probe | Zendy

Kudrik Evgeny V. | Zendy; Sorokin Alexander B. | Zendy

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N‐Bridged Diiron Phthalocyanine Catalyzes Oxidation of Benzene with H 2 O 2 via Benzene Oxide with NIH Shift Evidenced by Using 1,3,5‐[D 3 ]Benzene as a Probe

Author(s) -

Kudrik Evgeny V.,

Sorokin Alexander B.

Publication year - 2008

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200800504

Subject(s) - benzene , kinetic isotope effect , chemistry , oxide , phthalocyanine , phenol , photochemistry , kinetics , medicinal chemistry , inorganic chemistry , organic chemistry , deuterium , physics , quantum mechanics

Kinetic isotope effect : Incorporation of 18 O from H 2 18 O 2 in phenol in the presence of H 2 16 O and 16 O 2 and detection of benzene oxide as well as NIH shift in the course of the oxidation of PhH indicates that μ‐nitrido diiron phthalocyanine operates by a biooxidation‐like mechanism (see figure).

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