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Mononuclear Biscarbene Complexes by Direct Nucleophile Addition to a CO Ligand of Fischer Arylcarbene Complexes
Author(s) -
Barluenga José,
Trabanco Andrés A.,
PérezSánchez Iván,
De la Campa Raquel,
Flórez Josefa,
GarcíaGranda Santiago,
Aguirre Ángel
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200800452
Subject(s) - carbene , ligand (biochemistry) , nucleophile , chemistry , stereoselectivity , aryl , stereochemistry , combinatorial chemistry , medicinal chemistry , catalysis , organic chemistry , receptor , biochemistry , alkyl
Adding up carbene ligands : The unusual addition of some nucleophiles to a CO ligand of Fischer aryl carbene complexes has been developed and represents a novel and efficient approach to achieve once again the CO ligand → carbene ligand conversion. The potential of this methodology for the stereoselective synthesis of electron‐rich 1,3‐dienes is presented (see scheme).