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Isomeric Effect on Microscale Self‐Assembly: Interplay between Molecular Property and Solvent Polarity in the Formation of 1 D n ‐Type Microbelts
Author(s) -
Wang JieYu,
Yan Jing,
Li Zhendong,
Han JiMin,
Ma Yuguo,
Bian Jiang,
Pei Jian
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200800396
Subject(s) - microscale chemistry , polarity (international relations) , series (stratigraphy) , type (biology) , substitution (logic) , computer science , self assembly , solvent polarity , chemical physics , semiconductor , molecule , solvent , nanotechnology , chemistry , materials science , psychology , optoelectronics , organic chemistry , geology , biochemistry , paleontology , mathematics education , cell , programming language
The number of substituents and the different substitution patterns in a series of truxenone derivatives (see picture) greatly affected their molecular properties; this is clearly manifested in their different behaviors in self‐assembly and the resulting 1D microstructures. This series of molecules represents a new family of one‐dimensional organic n ‐type semiconductors.