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Three‐Dimensional Shape‐Persistent Fluorescent Nanocages: Facile Dynamic Synthesis, Photophysical Properties, and Surface Morphologies
Author(s) -
Luo Jia,
Lei Ting,
Xu Xiaoguang,
Li FangMei,
Ma Yuguo,
Wu Kai,
Pei Jian
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200800154
Subject(s) - nanocages , fluorescence , covalent bond , nanotechnology , chemistry , materials science , optics , organic chemistry , physics , catalysis
Enjoy orthogonally modifying : A readily modifiable structure was developed to quantitatively build a series of 3D shape‐persistent fluorescent nanocages (see figure) through dynamic covalent chemistry. The dynamic formation processes of the nanocages, directed by multivalent effects, were also observed. Interestingly, through simply adjusting the side chains, different surface morphologies of the nanocages were successfully achieved.