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Phosphorescent Iridium(III) Complexes with Nonconjugated Cyclometalated Ligands
Author(s) -
Song YiHwa,
Chiu YuanChieh,
Chi Yun,
Cheng YiMing,
Lai ChengHsuan,
Chou PiTai,
Wong KenTsung,
Tsai MingHan,
Wu ChungChih
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200800050
Subject(s) - phosphorescence , iridium , quantum efficiency , oled , photochemistry , chromophore , dopant , phosphorescent organic light emitting diode , materials science , brightness , chemistry , fluorescence , optoelectronics , catalysis , nanotechnology , physics , organic chemistry , doping , optics , layer (electronics)
Abstract A series of blue phosphorescent iridium(III) complexes 1 – 4 with nonconjugated N‐benzylpyrazole ligands were synthesized and their structural, electrochemical, and photophysical properties were investigated. Complexes 1 – 4 exhibit phosphorescence with yields of 5–45 % in degassed CH 2 Cl 2 . Of the compounds, 1 showed emission that was nearly true blue at 460 nm with a lack of vibronic progression. These photophysical data clearly demonstrate that the methylene spacer of the cyclometalated N‐benzylpyrazole chelate effectively interrupts the π conjugation upon reacting with a third L^X chelating chromophore. This gives a feasible synthesis for the blue phosphorescent complexes with a sufficiently large energy gap. In another approach, these complexes were investigated for their suitability for the host material in phosphorescent OLEDs. The device was synthesized by using 1 as the host for the green‐emitting [Ir(ppy) 3 ] dopant, which exhibits an external quantum conversion efficiency (EQE) of up to 11.4 % photons per electron (and 36.6 cdA −1 ), with 1931 Commission Internationale de L'Eclairage (CIE) coordinates of (0.30, 0.59), a peak power efficiency of 21.7 lmW −1 , and a maximum brightness of 32000 cdm −2 at 14.5 V. At the practical brightness of 100 cdm −2 , the efficiency remains above 11 % and 18 lmW −1 , demonstrating its great potential as the host material for phosphorescent organic light‐emitting diodes.