Chiral Bidentate Bis(N‐Heterocyclic Carbene)‐Based Palladium Complexes Bearing Carboxylate Ligands: Highly Effective Catalysts for the Enantioselective Conjugate Addition of Arylboronic Acids to Cyclic Enones | Zendy

Zhang Tao | Zendy; Shi Min | Zendy

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Chiral Bidentate Bis(N‐Heterocyclic Carbene)‐Based Palladium Complexes Bearing Carboxylate Ligands: Highly Effective Catalysts for the Enantioselective Conjugate Addition of Arylboronic Acids to Cyclic Enones

Author(s) -

Zhang Tao,

Shi Min

Publication year - 2008

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200701982

Subject(s) - carbene , denticity , conjugate , chemistry , palladium , enantioselective synthesis , carboxylate , chelation , catalysis , adduct , medicinal chemistry , polymer chemistry , stereochemistry , organic chemistry , crystal structure , mathematics , mathematical analysis

Axially chiral cis ‐chelated bidentate bis(N‐heterocyclic carbene)–palladium(II) complexes with two weakly coordinating carboxylate ligands are effective catalysts for the asymmetric conjugate addition of arylboronic acids to cyclic enones, producing the corresponding adducts in moderate‐to‐high yields and with good‐to‐high enantioselectivities, in most cases under mild conditions.

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