Systematic Reactions of [Pt(PF 3 ) 4 ] | Zendy

Drews Thomas | Zendy; Rusch Dieter | Zendy; Seidel Stefan | Zendy; Willemsen Stefan | Zendy; Seppelt Konrad | Zendy

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Systematic Reactions of [Pt(PF 3 ) 4 ]

Author(s) -

Drews Thomas,

Rusch Dieter,

Seidel Stefan,

Willemsen Stefan,

Seppelt Konrad

Publication year - 2008

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200701786

Subject(s) - tetrahedron , planar , trigonal bipyramidal molecular geometry , chemistry , crystallography , square (algebra) , cluster (spacecraft) , platinum , crystal structure , mathematics , catalysis , geometry , organic chemistry , computer graphics (images) , computer science , programming language

Tetrahedral [Pt(PF 3 ) 4 ] reacts with H + to form trigonal bipyramidal [Pt(PF 3 ) 4 H] + . This in turn looses PF 3 to form square‐planar [Pt(PF 3 ) 3 H] + . The complex [Pt(PF 3 ) 4 ] can be oxidized with AsF 5 to form the square‐planar complex, [Pt(PF 3 ) 4 ] 2+ , which can be more conveniently obtained from PtF 4 and PF 3 in HF/SbF 5 solution. [Pt(PF 3 ) 4 ] 2+ reacts with F − in HF under cluster formation to [Pt 4 (PF 3 ) 8 H] + .

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