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Polycyano‐Anion‐Based Energetic Salts
Author(s) -
Gao Haixiang,
Zeng Zhuo,
Twamley Brendan,
Shreeve Jean'ne M.
Publication year - 2008
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200701133
Subject(s) - ion , nitrogen , chemistry , nitride , inorganic chemistry , standard enthalpy of formation , carbon fibers , hydrogen bond , hydrogen , computational chemistry , organic chemistry , materials science , molecule , composite number , layer (electronics) , composite material
Energetic salts based on polycyano anions and cations with a high nitrogen content tend to have extensive hydrogen bonding and exhibit heats of formation up to Δ H f =1579.1 kJ mol −1 . Based on theoretical calculations, some of the new salts may be considered to be low‐energy monopropellants. One of the salts can be used as a precursor to a carbon nitride.
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