Infrared Spectrum and Structure of Thorimine (HNThH 2 ) | Zendy

Wang Xuefeng | Zendy; Andrews Lester | Zendy; Marsden Colin J. | Zendy

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Infrared Spectrum and Structure of Thorimine (HNThH 2 )

Author(s) -

Wang Xuefeng,

Andrews Lester,

Marsden Colin J.

Publication year - 2007

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200700183

Subject(s) - thorium , actinide , reactivity (psychology) , chemistry , imine , infrared , ammonia , atomic orbital , bond length , infrared spectroscopy , inorganic chemistry , crystallography , physics , crystal structure , nuclear physics , catalysis , organic chemistry , uranium , medicine , alternative medicine , pathology , electron , optics

Laser‐ablated thorium atoms react with ammonia to form thorimine (NHThH 2 ), the first actinide imine to be reported. This work underscores the high reactivity of thorium atoms, particularly for NH bond activation, reveals a new type of multiple bond to actinide atoms, and shows that this bond is strong for thorium as a result of an important contribution from the f orbitals.

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