A State‐of‐the‐Art Cyanation of Aryl Bromides: A Novel and Versatile Copper Catalyst System Inspired by Nature | Zendy

Schareina Thomas | Zendy; Zapf Alexander | Zendy; Mägerlein Wolfgang | Zendy; Müller Nikolaus | Zendy; Beller Matthias | Zendy

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A State‐of‐the‐Art Cyanation of Aryl Bromides: A Novel and Versatile Copper Catalyst System Inspired by Nature

Author(s) -

Schareina Thomas,

Zapf Alexander,

Mägerlein Wolfgang,

Müller Nikolaus,

Beller Matthias

Publication year - 2007

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200700079

Subject(s) - cyanation , reagent , aryl , catalysis , cyanide , copper , combinatorial chemistry , chemistry , halide , substrate (aquarium) , selectivity , ligand (biochemistry) , organic chemistry , biochemistry , alkyl , oceanography , receptor , geology

A general protocol for the cyanation of aryl halides with the nontoxic cyanide source K 4 [Fe(CN) 6 ] using copper catalysis and a ligand system based on 1‐alkylimidazoles is presented. The advantages of this system are the high selectivity, a unique substrate range, easy handling, and inexpensive reagents.

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