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Cover Picture: Functionalization of Heteropolyanions—Osmium and Rhenium Nitrido Derivatives of Keggin‐ and Dawson‐Type Polyoxotungstates: Synthesis, Characterization and Multinuclear ( 183 W, 15 N) NMR, EPR, IR, and UV/Vis Fingerprints (Chem. Eur. J. 36/2006)
Author(s) -
Dablemont Céline,
Hamaker Christopher G.,
Thouvenot René,
Sojka Zbigniew,
Che Michel,
Maatta Eric A.,
Proust Anna
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200690114
Subject(s) - electron paramagnetic resonance , osmium , cyclic voltammetry , rhenium , polyoxometalate , chemistry , characterization (materials science) , crystallography , inorganic chemistry , electrochemistry , materials science , ruthenium , organic chemistry , nanotechnology , nuclear magnetic resonance , physics , electrode , catalysis
Polyoxometalates or POM are remarkable because of their molecular and electronic tunability, and their range of properties and applications. In their Full Paper on page 9150 ff., E. A. Maatta, A. Proust et al. discuss various routes to nitrido derivatives, which may act as nitrogen‐atom transfer reagents to organic substrates. 183 W and 15 N NMR, EPR, IR, and UV/Vis spectroscopies and cyclic voltammetry have been used to address their electronic and molecular structures.