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Cover Picture: Kinetic, Thermodynamic, and Mechanistic Patterns for Free (Unbound) Cytochrome c at Au/SAM Junctions: Impact of Electronic Coupling, Hydrostatic Pressure, and Stabilizing/Denaturing Additives (Chem. Eur. J. 27/2006)
Author(s) -
Khoshtariya Dimitri E.,
Dolidze Tina D.,
Seifert Stefan,
Sarauli David,
Lee Geoffrey,
van Eldik Rudi
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200690086
Subject(s) - hydrostatic pressure , chemistry , coupling (piping) , adiabatic process , monolayer , kinetic energy , cover (algebra) , chemical physics , thermodynamics , crystallography , materials science , physics , classical mechanics , biochemistry , mechanical engineering , engineering , metallurgy
The cross‐testing of the CytC intrinsic ET mechanisms at the Au/SAM junctions (hydroxy‐terminated n ‐alkanethiol self‐assembled monolayers) in the freely diffusing regime revealed a gradual turnover from the adiabatic to nonadiabatic mechanism through the intermediate regime. In their Full Paper on page 7041 ff., R. van Eldik, D. E. Khoshtariya et al. describe their investigations involving variation of the SAM thickness ( n= 2, 3, 4, 6, 11, with n =4 found to be a turnover point), the relative solution viscosity, and the hydrostatic pressure (up to 150 MPa).