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Cover Picture: A Highly Tunable Family of Chiral Bisphospholanes for Rh‐Catalyzed Enantioselective Hydrogenation Reactions (Chem. Eur. J. 19/2006)
Author(s) -
Holz Jens,
Zayas Odalys,
Jiao Haijun,
Baumann Wolfgang,
Spannenberg Anke,
Monsees Axel,
Riermeier Thomas H.,
Almena Juan,
Kadyrov Renat,
Börner Armin
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200690057
Subject(s) - enantioselective synthesis , phosphine , cover (algebra) , catalysis , simple (philosophy) , toolbox , chemistry , wrench , combinatorial chemistry , computer science , materials science , organic chemistry , engineering , mechanical engineering , metallurgy , philosophy , epistemology , programming language
Just like a wrench fits any bolt, the catASium M toolbox offers tools for various applications. This tool box has been developed by using a simple and convergent strategy to synthesize one of the most comprehensive family of chiral bisphosphine ligands. In their Full Paper on page 5001 ff., J. Holz, A. Monsees, A. Börner et al. describe how this methodology, which can be easily scaled up for industrial requirements, was used for the construction of closely related bisphospholanes, differing in the size of the natural bite angles and σ‐donor properties of the phosphine.