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Polymeric Organometallic Architectures of Novel PSe Anions
Author(s) -
Shi Weifeng,
ShafaeiFallah Maryam,
Zhang Le,
Anson Christopher E.,
Matern Eberhard,
Rothenberger Alexander
Publication year - 2007
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200600626
Subject(s) - reagent , nucleophile , polymer , group 2 organometallic chemistry , solvent , ring (chemistry) , chemistry , polymer chemistry , metal , organometallic chemistry , curse of dimensionality , combinatorial chemistry , materials science , organic chemistry , molecule , catalysis , computer science , machine learning
The characterisation of a series of compounds obtained from Woollins' reagent (W.R.) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring‐opening reactions of W.R. with metal salts and crystallisation using solvent‐diffusion techniques. One‐dimensional coordination polymers are formed as a result, and we demonstrate that the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements.