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Phane Properties of [2.2]Paracyclophane/Dehydrobenzoannulene Hybrids
Author(s) -
Hinrichs Heino,
Boydston Andrew J.,
Jones Peter G.,
Hess Kirsten,
Herges Rainer,
Haley Michael M.,
Hopf Henning
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200600498
Subject(s) - hybrid , mathematics , biology , botany
A series of [2.2]paracyclophane/dehydrobenzo[14]annulene (PC/DBA) hybrids (hydrocarbons 5 , 6 , 9 , 10 b , and 10 c ), [2.2]paracyclophane/dehydro[14]annulene (PC/DA) hybrids ( 7 and 8 ) and suitable model systems ( 11 , 12 , and 33 ) has been synthesized. Comparison of the electronic absorption spectra in each series of compounds provides further insight into the global communication between the decks in the [2.2]paracyclophane unit.