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Toward the Synthesis of the Antibiotic Branimycin: Novel Approaches to Highly Substituted cis ‐Decalin Systems
Author(s) -
Mulzer Johann,
Castagnolo Daniele,
Felzmann Wolfgang,
Marchart Stefan,
Pilger Christian,
Enev Valentin S.
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200600279
Subject(s) - decalin , intramolecular force , nitrile , chemistry , stereoselectivity , ring (chemistry) , stereochemistry , metathesis , combinatorial chemistry , organic chemistry , catalysis , polymerization , polymer
A variety of highly functionalized cis ‐decalin systems have been prepared by means of the stereoselective transannular Diels–Alder (TADA) reaction of a ( Z , E , Z , Z )‐tetraene macrolide, and by means of intramolecular nitrile oxide olefin (INOC) or ring‐closing metathesis (RCM) annulations to quinic acid derivatives.

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