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A Spontaneous Combustion Reaction for Synthesizing Pt Hollow Capsules Using Colloidal Carbon Spheres as Templates
Author(s) -
Yang Ruizhi,
Li Hong,
Qiu Xinping,
Chen Liquan
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200501474
Subject(s) - carbon fibers , spheres , combustion , materials science , soot , chemical engineering , tube furnace , template , spontaneous combustion , hydrogen , colloid , nanoparticle , catalysis , tube (container) , nanotechnology , chemistry , composite material , organic chemistry , physics , astronomy , composite number , engineering
Here we report a spontaneous combustion reaction in synthesizing Pt hollow capsules. In brief, Pt nanoparticles were loaded on the surface of colloidal carbon spheres by wet‐chemical impregnation. When Pt‐loaded carbon spheres were taken out of an argon‐filled tube furnace at room temperature and exposed to air, they underwent spontaneous combustion. The internal carbon spheres templates were removed to leave nanostructured Pt hollow capsules. There are at least two critical conditions for the occurrence of the spontaneous combustion: the Pt particle size is below 5.8 nm, and the hydrogen content in the carbon spheres is above 2.570 wt %. Such a reaction is interesting for the preparation of metal hollow spheres and is also relevant with respect to removal of accumulated carbon on catalysts and for soot oxidation at room temperature.