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Manipulation of the Morphology of Semiconductor‐Based Nanostructures from Core–Shell Nanoparticles to Nanocables: The Case of CdSe/SiO 2
Author(s) -
Wang Zhenyang,
Lu Qifei,
Kong Mingguang,
Zhang Lide
Publication year - 2007
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200501425
Subject(s) - nanowire , materials science , photoluminescence , quantum dot , nanostructure , nanoparticle , nanotechnology , chemical vapor deposition , vaporization , semiconductor , chemical engineering , absorption (acoustics) , shell (structure) , core (optical fiber) , optoelectronics , composite material , chemistry , organic chemistry , engineering
The morphology of CdSe/SiO 2 was manipulated from core–shell‐structured nanoparticles to nanocables by using a chemical vapor deposition (CVD) process. The growth of nanocables, with cores no more than 20 nm in diameter, is initiated by the formation of core–shell nanoparticles with SiO 2 as matrix and CdSe clusters dispersed inside. After the subsequent vaporization of the SiO 2 matrix, the follow‐up CdSe vapor crystallizes with the remaining CdSe clusters as nuclei to form CdSe nanowires as the furnace was cooled to 1200 °C. During the controlled cooling of the furnace, the SiO vapor re‐deposits to sheathe the nanowires. The thickness of the shell and the diameter of core were successfully controlled. The photoluminescence measurements show that the CdSe/SiO 2 nanocables have strong visible‐light emission bands located at 590 and 688 nm, which are attributed to the defects induced by SiO 2 sheaths nanowires and the quantum confinement effect of the CdSe, respectively. The UV/Vis absorption spectra of the naked CdSe nanowires further validate the above‐mentioned quantum confinement effect. The deterministic growth of these nanocables is very important for the design of the nanodevices based on them.