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Design and Synthesis of Novel Propellanes by Using Claisen Rearrangement and Ring‐Closing Metathesis as the Key Steps
Author(s) -
Kotha Sambasivarao,
Dipak Mirtunjay Kumar
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200501366
Subject(s) - claisen rearrangement , ring closing metathesis , metathesis , chemistry , ring (chemistry) , stereochemistry , closing (real estate) , salt metathesis reaction , combinatorial chemistry , organic chemistry , political science , law , polymerization , polymer
Novel hexacyclic caged compounds are prepared by a combination of Claisen rearrangement and ring‐closing metathesis (RCM). Additionally, a Grignard reaction in conjugation with RCM produced intricate hexacyclic caged molecules.
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