Protonic and Temperature Modulation of Constituent Expression by Component Selection in a Dynamic Combinatorial Library of Imines | Zendy

Giuseppone Nicolas | Zendy; Lehn JeanMarie | Zendy

Premium

Protonic and Temperature Modulation of Constituent Expression by Component Selection in a Dynamic Combinatorial Library of Imines

Author(s) -

Giuseppone Nicolas,

Lehn JeanMarie

Publication year - 2006

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200501038

Subject(s) - biological system , ionic bonding , stimulus (psychology) , effector , computer science , expression (computer science) , chemistry , component (thermodynamics) , physics , biology , thermodynamics , biochemistry , psychology , ion , organic chemistry , cognitive psychology , programming language

The constitutional recomposition of a dynamic library of imines displays a complex behavior under the effect of two parameters, acidity and temperature. A qualitative analysis of the quantitative data is presented. The results illustrate the response of such a dynamic system to a physical stimulus (temperature) and a chemical effector (H + ), thus demonstrating its adaptive behavior under the pressure of external factors. They also point to the possibility of modulating a given functional property (optical, electronic, ionic) by constitutional recomposition induced by a specific trigger. Such features are of great interest for the development of stimuli‐responsive, functional dynamic materials.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research