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Protonic and Temperature Modulation of Constituent Expression by Component Selection in a Dynamic Combinatorial Library of Imines
Author(s) -
Giuseppone Nicolas,
Lehn JeanMarie
Publication year - 2006
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200501038
Subject(s) - biological system , ionic bonding , stimulus (psychology) , effector , computer science , expression (computer science) , chemistry , component (thermodynamics) , physics , biology , thermodynamics , biochemistry , psychology , ion , organic chemistry , cognitive psychology , programming language
The constitutional recomposition of a dynamic library of imines displays a complex behavior under the effect of two parameters, acidity and temperature. A qualitative analysis of the quantitative data is presented. The results illustrate the response of such a dynamic system to a physical stimulus (temperature) and a chemical effector (H + ), thus demonstrating its adaptive behavior under the pressure of external factors. They also point to the possibility of modulating a given functional property (optical, electronic, ionic) by constitutional recomposition induced by a specific trigger. Such features are of great interest for the development of stimuli‐responsive, functional dynamic materials.