A New Approach to Enantiopure  C  3 ‐Symmetric Molecules | Zendy

Castaldi M. Paola | Zendy; Gibson Susan E. | Zendy; Rudd Matthew | Zendy; White Andrew J. P. | Zendy

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A New Approach to Enantiopure C 3 ‐Symmetric Molecules

Author(s) -

Castaldi M. Paola,

Gibson Susan E.,

Rudd Matthew,

White Andrew J. P.

Publication year - 2005

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200501031

Subject(s) - enantiopure drug , ruthenium , molecule , substrate (aquarium) , chemistry , triol , stereochemistry , combinatorial chemistry , combinatorics , computational chemistry , mathematics , enantioselective synthesis , organic chemistry , catalysis , diol , oceanography , geology

Chiral base chemistry has been used to create three chiral centres in one pot on a C 3 ‐symmetric substrate. The potential of this new approach to C 3 ‐symmetric molecules is exemplified by the creation of an enantiopure C 3 v ‐symmetric triol, triphosphane and tripyridine. A ruthenium complex of the last compound has been studied by X‐ray crystallography.

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