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Significant Enhancement of the Stille Reaction with a New Combination of Reagents—Copper( I ) Iodide with Cesium Fluoride
Author(s) -
Mee Simon P. H.,
Lee Victor,
Baldwin Jack E.
Publication year - 2005
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200401162
Subject(s) - stille reaction , iodide , reagent , fluoride , copper , chemistry , caesium , iodine , steric effects , inorganic chemistry , organic chemistry , catalysis
The combination of copper( I ) iodide and cesium fluoride significantly enhances the Stille reaction. After extensive optimisation, a variety of electronically unfavourable and sterically hindered substrates were coupled in very high yields under mild conditions.