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The Structural Influence in the Stability of Polymer‐Bound Diazonium Salts
Author(s) -
Bräse Stefan,
Dahmen Stefan,
Popescu Crisan,
Schroen Maarten,
Wortmann FranzJosef
Publication year - 2004
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200400386
Subject(s) - counterion , thermal stability , polymer , kinetics , polymer chemistry , chemistry , ion , materials science , chemical engineering , organic chemistry , physics , quantum mechanics , engineering
Abstract Various new diazonium ions on a polymeric support that have a variety of counterions and complexation with crown ethers have been prepared, and the thermal stability of these resins over a larger temperature interval has been investigated. Nonisothermal kinetics applied to DSC data have been used predicting the lifetime of the resins.