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Retention of Configuration in the Nucleophilic Substitution Reactions of Some Nine‐Membered Ansa Derivatives of Cyclotriphosphazatriene
Author(s) -
Beşli Serap,
Coles Simon J.,
Davies David B.,
Hursthouse Michael B.,
İbişoǧlu Hanife,
Kılıç Adem,
Shaw Robert A.
Publication year - 2004
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200400311
Subject(s) - nucleophilic substitution , substitution (logic) , chemistry , substitution reaction , walden inversion , nucleophile , stereochemistry , nucleophilic aromatic substitution , crystallography , medicinal chemistry , organic chemistry , catalysis , computer science , programming language
X‐ray crystallographic evidence shows that nucleophilic substitution reactions of two different types of cyclophosphazene derivatives with relatively rigid nine‐membered ansa rings leads to the first demonstration of retention of configuration in these molecular systems.