Synthesis of an Amino‐Functionalized Model of the Fe‐Only Hydrogenase Active Site | Zendy

Salyi Szabolcs | Zendy; Kritikos Mikael | Zendy; Åkermark Björn | Zendy; Sun Licheng | Zendy

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Synthesis of an Amino‐Functionalized Model of the Fe‐Only Hydrogenase Active Site

Author(s) -

Salyi Szabolcs,

Kritikos Mikael,

Åkermark Björn,

Sun Licheng

Publication year - 2003

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200390058

Subject(s) - active site , hydrogenase , supramolecular chemistry , chemistry , linkage (software) , electron transfer , stereochemistry , combinatorial chemistry , crystallography , crystal structure , enzyme , biochemistry , photochemistry , gene

A dinuclear 2Fe2S mimic 6 of the active site of the Fe‐only hydrogenases has been synthesized. Complex 6 contains a free amino group which enables linkage to a protein backbone or to a redox active species for the study of electron transfer processes in proteins or in supramolecular systems. The structures of the complex 6 and its Boc‐protected precursor 5 could be verified by X‐ray crystallography.

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