Cesium Fluoride–Bromine Intercalation Compounds | Zendy

Drews Thomas | Zendy; Marx Ruppert | Zendy; Seppelt Konrad | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Cesium Fluoride–Bromine Intercalation Compounds

Author(s) -

Drews Thomas,

Marx Ruppert,

Seppelt Konrad

Publication year - 1996

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.19960021018

Subject(s) - bromine , intercalation (chemistry) , chemistry , chlorine , molecule , iodine , caesium , fluoride , inorganic chemistry , medicinal chemistry , organic chemistry

CsF reacts with Br 2 to form the two intercalation compounds CsF·Br 2 and 2CsF·Br 2 . The former consists of layers of CsF squares separated by layers of Br 2 molecules oriented perpendicular to the CsF layers. 2CsF·Br 2 is a second‐stage compound, composed of two layers of CsF followed by one layer of bromine molecules. Iodine cannot replace bromine; instead, it reacts with CsF to form Cs 2 I 8 , and probably CsIF 6 between 0° and 120 °C. Chlorine does not react at all with CsF. Bromine reacts with RbF only superficially, and after a long time some RbBr 3 is observed; RbF and I 2 give RbI 3 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research