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Novel Sulfur‐Containing Inorganic Aprotic Superacids as Effective Initiators of Low‐Temperature Cracking and Isomerization of Alkanes
Author(s) -
Akhrem Irena,
Gudima Svetlana,
Vol'pin Mark
Publication year - 1996
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.19960020713
Subject(s) - isomerization , chemistry , sulfur , halide , cracking , aluminium , chloride , inorganic chemistry , polymer chemistry , organic chemistry , catalysis
Abstract A novel family of inorganic aprotic superacids has been found. Oxochlorides and chloride of sulfur combined with aluminium halides (SOCl 2 · n AlX 3 , SO 2 Cl 2 · n AlX 3 , MeSO 2 Cl· n AlX 3 , CF 3 SO 2 Cl· n AlX 3 , S 2 Cl 2 · n AlX 3 ; n = 2 or 3, X = Br or Cl) are found to be effective promoters for the cracking and isomerization of alkanes at room temperature.