NUO + , a New Species Isoelectronic to the Uranyl Dication UO       2    2+ | Zendy

Heinemann Christoph | Zendy; Schwarz Helmut | Zendy

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NUO + , a New Species Isoelectronic to the Uranyl Dication UO 2 2+

Author(s) -

Heinemann Christoph,

Schwarz Helmut

Publication year - 1995

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.19950010105

Subject(s) - uranyl , dication , uranium , chemistry , dissociation (chemistry) , ion , molecule , actinide , inorganic chemistry , density functional theory , computational chemistry , crystallography , organic chemistry , nuclear physics , physics

The nitridooxouranium cation NUO + has been prepared as a new isoelectronic homologue to the uranyl dication UO 2 2+ by a sequence of ionmolecule reactions starting from the atomic uranium cation U + . Collision‐induced dissociation experiments and ligand‐exchange reactions serve to unambiguously identify the ion as a species in which the uranium cation is formally inserted in the NO molecule. New thermochemical data for NUO + and UN + are given, and the stability of NUO + with respect to UO 2 2+ is investigated by means of quasi‐relativistic density‐functional calculations.

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