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The synthesis of carbon microspheres film composed of nano‐onions and its application as flexible supercapacitors
Author(s) -
Zhang Miao,
Zhao Naiqin,
Li Xifei
Publication year - 2021
Publication title -
carbon energy
Language(s) - English
Resource type - Journals
ISSN - 2637-9368
DOI - 10.1002/cey2.90
Subject(s) - supercapacitor , materials science , nanotechnology , fabrication , electrochemistry , carbon fibers , chemical vapor deposition , nano , composite number , electrode , chemical engineering , current density , composite material , chemistry , medicine , alternative medicine , physics , pathology , quantum mechanics , engineering
Flexible electrodes with superior mechanical and electrochemical properties are essential for flexible supercapacitors. A convenient and scalable colloidal film‐assisted chemical vapor deposition (CF‐CVD) method is developed for the one‐step fabrication of the carbon microspheres films composed of carbon nano‐onions (CMS‐CNO films). The influence of growth conditions (such as growth temperature, time, and gas ratio) during CF‐CVD process on the carbon structures and the growth mechanism of the CMS‐CNO films have been investigated. By controlling the growth conditions, the controllable preparation of CMS‐CNO films is realized. Such binder‐free films can be used for the assembly of flexible supercapacitors, and unique architecture can achieve excellent performance. Benefitting from the composite of nano‐micro zero dimensional structures, the performance of the film in supercapacitors is remarkably improved. At the current density of 5 mA cm −2 , the area‐specific capacity can be 903 mF cm −2 . When the current density is increased to 500 mA cm −2 , the area‐specific capacity can be increased to 729 mF cm −2 . This simple and low‐cost preparation process and the superb electrochemical performance suggest great potential applications of CMS‐CNO films in flexible supercapacitors.

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