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Cover Feature: Electron Transfer Inside a Decaferrocenylated Rotaxane Analyzed by Fast Scan Cyclic Voltammetry and Impedance Spectroscopy (ChemElectroChem 18/2021)
Author(s) -
BoitelAullen Gabriel,
Fillaud Laure,
Huet François,
Nierengarten Iwona,
DelavauxNicot Béatrice,
Nierengarten JeanFrançois,
Maisonhaute Emmanuel
Publication year - 2021
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.202101039
Subject(s) - cyclic voltammetry , rotaxane , dielectric spectroscopy , electron transfer , ferrocene , cover (algebra) , electrical impedance , materials science , redox , electron , analytical chemistry (journal) , chemistry , crystallography , photochemistry , electrochemistry , electrode , electrical engineering , physics , inorganic chemistry , organic chemistry , supramolecular chemistry , mechanical engineering , quantum mechanics , crystal structure , engineering
The Cover Feature shows an artistic view of a decaferrocenylated pillar[5]arene‐based rotaxane grafted onto a gold surface. Complementary fast scan cyclic voltammetry and impedance measurements revealed that all the redox centers are not equivalent. They display effectively different electron transfer rate constants suggesting a distribution of distances between the ferrocene moieties and the surface. More information can be found in the Article by J.‐F. Nierengarten, E. Maisonhaute et al.