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2D Heterojunction Between Double Perovskite Oxide Nanosheet and Layered Double Hydroxide to Promote Rechargeable Zinc‐Air Battery Performance
Author(s) -
Mondal Surajit,
Majee Rahul,
Arif Islam Quazi,
Bhattacharyya Sayan
Publication year - 2020
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.202001412
Subject(s) - bifunctional , overpotential , nanosheet , materials science , oxygen evolution , hydroxide , oxide , heterojunction , graphene , inorganic chemistry , chemical engineering , nanotechnology , chemistry , catalysis , electrochemistry , electrode , organic chemistry , optoelectronics , metallurgy , engineering
The role of two‐dimensional (2D) materials in electrocatalytic energy conversion reactions is unprecedented among which the earth‐abundant metal oxide nanosheets (NSs) that could promote bifunctional electrocatalytic oxygen reduction and evolution reactions (ORR/OER) remain elusive. <20 nm thick double perovskite oxide, Pr 0.5 Ba 0.5 Mn 1.8‐ x Nb x Co 0.2 O 6‐δ (PBMNC‐ x , x =0–0.3, δ=0.38–0.59) NSs having a lateral spread of ∼300 nm were designed with exsolved metallic Co and Co 3 O 4 nanoparticles (NPs) anchored to the NS surface. PBMNC‐0.1 NSs demonstrate the best ORR/OER bifunctional activity among all PBMNC‐ x samples with a bifunctionality index (BI) of 1.36 V, which is the combined OER and ORR overpotential (η) at 10 and−3 mA/cm 2 current density, respectively. To promote the OER performance, chemically attached 2D heterojunctions of PBMNC‐0.1 NS and y mol % of NiFe (3 : 1) layered double hydroxide (NiFe‐LDH) were hydrothermally synthesized. Among the PBMNC/LDH‐ y heterojunctions, PBMNC/LDH‐20 shows the lowest BI of 1.06 V because of an electronic reorganization at the heterojunction as evidenced from Mott‐Schottky analysis. Proof of concept rechargeable zinc‐air battery (r‐ZAB) with PBMNC/LDH‐20 cathode exhibits a specific capacity of 695.6 mA.h/g Zn and roundtrip charge‐discharge stability for 100 h at 5 mA/cm 2 , surpassing the performance of state‐of‐the‐art Pt/C‐RuO 2 couple.