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The Effect of Cation Mixing in LiNiO 2 toward the Oxygen Evolution Reaction
Author(s) -
Ren Yadan,
Yamaguchi Ryusei,
Uchiyama Tomoki,
Orikasa Yuki,
Watanabe Toshiki,
Yamamoto Kentaro,
Matsunaga Toshiyuki,
Nishiki Yoshinori,
Mitsushima Shigenori,
Uchimoto Yoshiharu
Publication year - 2021
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.202001207
Subject(s) - catalysis , chemistry , nickel , x ray absorption spectroscopy , inorganic chemistry , oxygen evolution , lithium (medication) , analytical chemistry (journal) , absorption spectroscopy , electrochemistry , medicine , biochemistry , physics , organic chemistry , electrode , quantum mechanics , chromatography , endocrinology
Nickel‐based oxide catalysts are widely used for the oxygen evolution reaction (OER) in alkaline water electrolysis because of their low cost and high activity. In particular, the LiNiO 2 catalyst shows high activity. Therefore, to elucidate the fundamental relationship between the local structure, catalyst activity, and stability of LiNiO 2 , we investigated the cation mixing effect by mixing sites of lithium and nickel ions in the LiNiO 2 ‐based catalysts. Lower degrees of cation mixing lead to higher intrinsic OER activity but lower long‐term stability. The X‐ray absorption spectra (XAS) displayed a strong hybridization state of the Ni 3d and O 2p orbitals, which is the origin of the different catalytic activity behaviors. Meanwhile, operando XAS studies combined with potentiostatic stability tests and inductively coupled plasma optical emission spectrometry (ICP‐OES) demonstrated the Li ion loss during the OER process. Thus, the instability of LiNiO 2 originates from de‐intercalation of Li ions and this irreversible structure change deteriorates the performance. Hindering the lithium diffusion path by cation mixing is a useful strategy for maintaining performance. This strategy could provide a novel design principle for compatible high activity and long‐lasting catalysts by reasonable structure mediation.