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Benefits of Organo‐Aqueous Binary Solvents for Redox Supercapacitors Based on Polyoxometalates
Author(s) -
Dsoke Sonia,
Abbas Qamar
Publication year - 2020
Publication title -
chemelectrochem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 59
ISSN - 2196-0216
DOI - 10.1002/celc.202000639
Subject(s) - redox , aqueous solution , electrochemistry , chemistry , polyoxometalate , electrolyte , adsorption , solvent , dimethyl sulfoxide , supercapacitor , moiety , inorganic chemistry , activated carbon , carbon fibers , materials science , organic chemistry , electrode , catalysis , composite material , composite number
A novel redox electrolyte is proposed based on organo‐aqueous solvent and a polyoxometalate (POM) redox moiety. The presence of dimethyl sulfoxide (DMSO) plays multiple roles in this system. Firstly, it enhances the cathodic electrochemical stability window by shifting the H 2 evolution to lower potentials with respect to pure aqueous systems; secondly, it improves the reversibility of the redox reaction of the PW 12 O 40 3− anion at low potentials. The presence of DMSO suppresses the Al corrosion, thus enabling the use of this metal as the current collector. An activated carbon‐based supercapacitor is investigated in 1 M LiNO 3 /10 mM H 3 PW 12 O 40 in a mixed DMSO/H 2 O solvent and compared with a POM‐free electrolyte. In the presence of POMs, the device achieves better stability under floating conditions at 1.8 V. At 1 kW kg −1 , it delivers a specific energy of 8 Wh kg −1 vs. 4.5 Wh kg −1 delivered from the POM‐free device. The H 2 evolution is further shifted by the POMs adsorbed on the activated carbon, which is one reason for the improved stability. The POM‐containing cell demonstrates a mitigated self‐discharge, owing to strong POMs adsorption into the carbon pores.